Name | 1-Bromododecane |
Synonyms | LAURYL BROMIDE Lauryl bromide Lauroylbromide 1-bromo-dodecan DODECYL BROMIDE 1-Bromododecane 1-Dodecylbromid 1-BROMODODECANE n-Dodecyl bromide N-DODECYL BROMIDE 1-BROMODECANE pure 1-BROMODODECANE pure |
CAS | 143-15-7 |
EINECS | 205-587-9 |
InChI | InChI=1/C12H25Br/c1-2-3-4-5-6-7-8-9-10-11-12-13/h2-12H2,1H3 |
InChIKey | PBLNBZIONSLZBU-UHFFFAOYSA-N |
Molecular Formula | C12H25Br |
Molar Mass | 249.23 |
Density | 1.040g/mLat 20°C |
Melting Point | −11-−9°C(lit.) |
Boling Point | 134-135°C6mm Hg(lit.) |
Flash Point | >230°F |
Water Solubility | insoluble |
Solubility | alcohol: soluble |
Vapor Presure | 0.00817mmHg at 25°C |
Vapor Density | 8.6 (vs air) |
Appearance | Liquid |
Color | Clear |
Merck | 14,5389 |
BRN | 506159 |
Storage Condition | Sealed in dry,2-8°C |
Stability | Stable. Combustible. Incompatible with strong oxidizing agents, strong bases. |
Refractive Index | n20/D 1.458(lit.) |
Physical and Chemical Properties | character colorless liquid. Irritating. |
Use | Mainly used in organic synthesis, used in medicine for the synthesis of disinfection drugs, such as new glycerin, and so on |
Hazard Symbols | Xi - Irritant |
Risk Codes | 36/37/38 - Irritating to eyes, respiratory system and skin. |
Safety Description | S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36 - Wear suitable protective clothing. S24/25 - Avoid contact with skin and eyes. |
WGK Germany | 3 |
FLUKA BRAND F CODES | 19 |
TSCA | Yes |
HS Code | 29033036 |
colorless to light yellow liquid with coconut-like odor. Melting Point -9.5 °c. Boiling point 276 °c. The relative density was 1. 0399. Refractive index 1.4583. Flash point 110 °c. Insoluble in water, soluble in ethanol, ether. Miscible with acetone. Irritating.
1. Hydrobromic acid method with decanediol as raw material, in the presence of sulfuric acid and hydrobromic acid reaction.
2. Sodium bromide method
3. Bromination method
used as a solvent, can also be used for the synthesis of flame retardant three (twelve alkyl mercaptan) antimony, antioxidant twelve alkyl mercaptan, surfactant dodecyl dimethyl benzyl ammonium chloride (benzalkonium chloride), and other flame retardants and surfactants.
toxic, long-term inhalation can cause neurological disorders. 200kg plastic barrel.
NIST chemical information | information provided by: webbook.nist.gov (external link) |
EPA chemical substance information | information provided by: ofmpeb.epa.gov (external link) |
Introduction | bromododecane is a halogenated hydrocarbon with the chemical formula C12H25Br, which can be used for the synthesis of neoglucene chloride and other chemicals. |
uses | is mainly used in organic synthesis, in medicine for the synthesis of disinfection drugs such as neoglucinamide, Mesilate, etc. Used as solvent, it can also be used for the synthesis of flame retardant antimony Tris (dodecylmercaptan), antioxidant dodecylmercaptan, surfactant dodecyldimethyl benzyl ammonium chloride (benzalkonium bromide), benzalkonium bromide, and other flame retardants and surfactants. used as solvent, also used in organic synthesis |
production method | 1. Hydrobromic acid method is derived from the interaction of lauryl alcohol (N-decanediol) and hydrobromic acid. Lauryl alcohol was added to the enamel glass reaction Pan, stirred and cooled, and sulfuric acid was slowly added. After stirring for 1H, additional hydrobromic acid was added. The temperature was gradually increased to 90-95 °c and the reaction was stirred for 8H. After completion of the reaction, the temperature was lowered to 30 °c and allowed to stand for 8H. The acid layer was separated, and the oil layer was adjusted to pH 8 with dilute alkali solution. The alkali solution was separated and washed with 50% ethanol. By distillation under reduced pressure, a fraction of 140-200 ° C. (3.33kPa) was collected to obtain purified 1-bromododecane. 2. Sodium bromide method 3. Bromination method |